Structure‐guided Capacitance Relationships in Oxidized Graphene Porous Materials Based Supercapacitors

نویسندگان

چکیده

Supercapacitors formed from porous carbon and graphene-oxide (GO) materials are usually dominated by either electric double-layer capacitance, pseudo-capacitance, or both. Due to these combined features, reduced GO have been shown offer superior capacitance over typical nanoporous materials; however, there is a significant variation in reported values, ranging between 25 350 F g−1. This undermines the structure (e.g., oxygen functionality and/or surface area)-performance relationships for optimization of cost scalable factors. work demonstrates important structure-controlled charge storage relationships. For this, series exfoliated graphene (EG) derivatives produced via thermal-shock exfoliation precursors following controlled graphitization EG (GEG) generates with varied amounts porosity, redox-active groups graphitic components. Experimental results show significantly values 30 250 g−1 at 1.0 A GEG structures; this suggests that given specific area hydrophilic content can boost 250–300% higher compared mesoporous materials. GEGs identical governed capacitance. allows establish direct structure-performance 1) functional concentration 2)

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ژورنال

عنوان ژورنال: Energy & environmental materials

سال: 2023

ISSN: ['2575-0348', '2575-0356']

DOI: https://doi.org/10.1002/eem2.12637